Enhanced Vibrations at Surfaces with Back-Bonds Nearly Parallel to the Surface†

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Enhanced Vibrations at Surfaces with Back-Bonds Nearly Parallel to the Surface

It has been discovered that several very different surfaces exhibit a common property: unusually large vibration amplitudes of the outermost atoms, well beyond the enhancement normally expected at typical clean surfaces. These special surfaces are: ice H2O(0001), α-Al2O3(0001), α-Ga(010) and Si(111)-(2x1). The root-mean-square vibration amplitudes in these surfaces are at least double the bulk ...

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ژورنال

عنوان ژورنال: The Journal of Physical Chemistry B

سال: 2004

ISSN: 1520-6106,1520-5207

DOI: 10.1021/jp040047x